Mathematical Treatment of Measurement Results Summary
Summary of lessons so far
Measurement Uncertainty, Accuracy, and Precision
Quantities can be exact or measured. Measured quantities have an associated uncertainty that is represented by the number of significant figures in the measurement. The uncertainty of a calculated value depends on the uncertainties in the values used in the calculation and is reflected in how the value is rounded. Measured values can be accurate (close to the true value) and/or precise (showing little variation when measured repeatedly).
Mathematical Treatment of Measurement Results
Measurements are made using a variety of units. It is often useful or necessary to convert a measured quantity from one unit into another. These conversions are accomplished using unit conversion factors, which are derived by simple applications of a mathematical approach called the factor-label method or dimensional analysis. This strategy is also employed to calculate sought quantities using measured quantities and appropriate mathematical relations.
Key Equations
- \(T_{^{\circ}\text{C}} = \frac{5}{9}(T_{^{\circ}\text{F}} - 32)\)
- \(T_{^{\circ}\text{F}} = \frac{9}{5} × T_{^{\circ}\text{C}} + 32\)
- \(T_{\text{K}} = T_{^{\circ}\text{C}} + 273.15\)
- \(T_{^{\circ}\text{C}} = T_{\text{K}} - 273.15\)
Glossary of Words
Accuracy
how closely a measurement aligns with a correct value
Dimensional analysis
(also, factor-label method) versatile mathematical approach that can be applied to computations ranging from simple unit conversions to more complex, multi-step calculations involving several different quantities
Exact number
number derived by counting or by definition
Fahrenheit
unit of temperature; water freezes at 32 °F and boils at 212 °F on this scale
Precision
how closely a measurement matches the same measurement when repeated
Rounding
procedure used to ensure that calculated results properly reflect the uncertainty in the measurements used in the calculation
Significant figures
(also, significant digits) all of the measured digits in a determination, including the uncertain last digit
Uncertainty
estimate of amount by which measurement differs from true value
Unit conversion factor
ratio of equivalent quantities expressed with different units; used to convert from one unit to a different unit
This lesson is part of:
Essential Ideas in Chemistry